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In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.

Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]

Poly[(μ₃-4-aminobenzenesulfonato-κ³N:O:O)(triphenylphosphine-κP)silver(I)]