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The mol­ecule of the title compound, C 8 H 13 NO 6 , a sucrose derivative, consists of two fused tetra­hydro­furan rings having the  cis  arrangement at the ring junctions, giving a V-shaped mol­ecule. An intra­molecular O—H⋯O inter­action occurs. Inter­molecular O—H⋯O hydrogen bonds help to stabilize the crystal structure.

(3R,3aS,6R,6aR)-3-(1-Nitroethyl)perhydrofuro[3,2-b]furan-3,6-diol