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In the title compound, [Mn(H 2 O) 6 ](C 16 H 12 O 6 )·H 2 O, the [Mn(H 2 O) 6 ] 2+  complex cation lies on a mirror plane, the 4,4′-(1,2-dihy­droxy­ethane-1,2-di­yl)dibenzoate anion is located on an inversion center and the solvent water mol­ecule also lies on a mirror plane. Extensive O—H⋯O hydrogen-bonding inter­actions between the cations, anions and water mol­ecules stabilize the three-dimensional network.

Hexaaquamanganese(II) 4,4′-(1,2-dihydroxyethane-1,2-diyl)dibenzoate monohydrate