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The title compound, C 36 H 34 N 4 O 4 S 2 , is a thio­glycoluril derivative, which bears two phenyl substituents on its convex face and two meth­oxy substituted  o -xylylenes as sidewalls of the molecular clip. There is one half-mol­ecule in the asymmetric unit: a crystallographic twofold axis generates the complete molecule. The non-planar seven-membered rings adopt chair conformations, while the two five-membered rings exhibit envelope conformations and make a dihedral angle of 68.46 (12)°. The O atoms of the meth­oxy groups are coplanar with the six-membered  o -xylylene sidewalls.

acta crystallographica. section e

3,6,14,17-Tetramethoxy-22,23-diphenyl-1,10,12,21-tetraazahexacyclo[19.2.1.02,7.010,23.012,22.013,18]tetracosa-2(7),3,5,13(18),14,16-hexaene-11,24-dithione