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In the title compound, [N(C 4 H 9 ) 4 ][V(C 23 H 21 NS 3 Si) 2 ]·4CH 3 CN, the V III  atom (site symmetry) is coordinated by two  N , S , S ′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1 H -4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ate ligands in a distorted  trans -VN 2 S 4  octa­hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol­ate precursor and reduction of nitrile to the imidate.

acta crystallographica. section e

Tetrabutylammonium bis[4,4′-dimethyl-2,2′-(3,7-dimethyl-1<i>H</i>-4,2,1-benzothiazasiline-1,1-diyl)dibenzenethiolato]vanadium(III) acetonitrile tetrasolvate

Tetrabutylammonium bis[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiazasiline-1,1-diyl)dibenzenethiolato]vanadium(III) acetonitrile tetrasolvate