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Facile ligand substitution is observed when the ruthenium–azide complex, [RuN 3 (Tp)(PPh 3 ) 2 ] [Tp,HB(pz) 3 , pz = pyrazol­yl, PPh 3  = triphenyl­phosphine] is treated with benzo­nitrile, yielding the title compound, [Ru(C 9 H 10 BN 6 )(N 3 )(C 7 H 5 N)(C 18 H 15 P)]. The asymmetric unit contains two crystallographically independent mol­ecules. In each one, the Ru II  atom is six-coordinated in a distorted octa­hedral geometry by five N atoms from an htpb ligand, an azide ligand and a benzonitrile ligand and one P atom from a triphenyl­phosphine (tpp) ligand. The azide group is almost linear and is coordinated to Ru with an average Ru—N—N angle of 124.9 (3)°.

Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II)

Azido(benzonitrile-κN)[hydridotris(pyrazol-1-yl-κN²)borato](triphenylphosphine-κP)ruthenium(II)