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The asymmetric unit of the title salt, {(C 12 H 20 N 4 )[Ag 2 Br 4 ]}  n  , contains one-half of a substituted imidazolium cation, one Ag +  and two Br −  ions. The cation is completed by crystallographic inversion symmetry. The crystal structure is made up from polymeric sheets of {[AgBr 2 ] − }  n   anions extending parallel to (100). The basic building unit of the anion is a slightly distorted AgBr 4  tetra­hedron. A four- and 12-membered ring system is formed by corner sharing of the AgBr 4  tetra­hedra. The imidazolium cations are located between the anionic sheets and partly protrude into the voids defined by the 12-membered rings.

Poly[3,3′-diethyl-1,1′-(ethane-1,2-diyl)diimidazolium [tetra-μ-bromido-diargentate(I)]]