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In the title compound, C 16 H 28 N 3 O 4 , the plane of the pyrrolidine ring system is twisted with respect to the plane of the nitronyl nitroxide unit, making a dihedral angle of 79.80 (6)°. The crystal structure is stabilized by C—H⋯O hydrogen bonds.

2-[1-(tert-Butoxycarbonyl)pyrrolidin-2-yl]-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide