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The asymmetric unit of the title Cd II  compound, [Cd(N 3 ) 2 (C 12 H 8 N 2 )]  n  , contains a Cd II  atom, located on a twofold axis passing through the middle of the phenanthroline mol­ecule, one azide ion and half of a 1,10-phenanthroline mol­ecule. The Cd II  atom exhibits a distorted octa­hedral coordin­ation including one chelating 1,10-phenanthroline ligand and four azide ligands. The crystal structure features chains along the  c  direction in which azide groups doubly bridge two adjacent Cd II  atoms in an end-on (EO) mode. Inter­chain π–π stacking inter­actions, with centroid–centroid separations of 3.408 (2) Å between the central aromatic rings of 1,10-phenanthroline mol­ecules, lead to a supra­molecular sheet parallel to the  bc  plane.

catena-Poly[di-μ1,1-azido-(1,10-phenanthroline)cadmium(II)]

catena-Poly[di-μ_1,1-azido-(1,10-phenanthroline)cadmium(II)]