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The title compound, [Ag 2 (NO 3 ) 2 (C 28 H 30 N 2 P 2 )]  n  , crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the  c  axis. The crystal used for the data collection was a racemic twin.

Poly[[μ2-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-μ4-nitrato-μ2-nitrato-silver(I)]

Poly[[μ₂-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-μ₄-nitrato-μ₂-nitrato-silver(I)]