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In the title compound, [Cu(CH 3 COO) 2 (C 18 H 16 N 2 O 2 )]·H 2 O, the Cu II  ion is six-coordinated in a typically Jahn–Teller distorted octa­hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter­molecular O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecules.

Bis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ4N,O,O′,N′]copper(II) monohydrate

Bis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ⁴N,O,O′,N′]copper(II) monohydrate