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In the title compound, [FeLi(C 29 H 41 N 2 )Cl 2 (C 4 H 10 O 2 ) 2 ], the Fe II  atom is coordinated by two N and two Cl atoms, generating a distorted FeN 2 Cl 2  tetra­hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy­ethane mol­ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.

acta crystallographica. section e

[N,N′-Bis(2,6-diisopropylphenyl)pentane-2,4-diamine(1–)-2κ2N,N′]-μ2-chlorido-1:2κ2Cl:Cl-chlorido-2κCl-bis(1,2-dimethoxyethane-1κ2O,O′)iron(II)lithium