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In the title compound, [Na(C 6 H 3 Cl 2 O 3 S)(H 2 O)]  n  , the Na I  ion is penta­coordinated by three dichloro­benzene­sulfonate anions and two water mol­ecules, forming a distorted trigonal-bipyramidal geometry. The Na I  ions are bridged by the sulfonate groups and the water mol­ecules, leading to a polymeric layer structure parallel to the  bc  plane in which O—H⋯O hydrogen bonds are observed.

Poly[μ2-aqua-(μ3-2,5-dichlorobenzenesulfonato)sodium]

Poly[μ₂-aqua-(μ₃-2,5-dichlorobenzenesulfonato)sodium]