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In the title compound, [Zn(C 8 H 5 NO 5 )(H 2 O) 5 ]·H 2 O, the Zn II  atom is coordinated by one O atom from the 2-(5-carboxyl­ato-2-oxidopyridinium-1-yl)acetate ligand and by five water mol­ecules, forming a distorted octa­hedral geometry. Coordinated and uncoordinated water mol­ecules form O—H⋯O hydrogen bonds, leading to a three-dimensional framework.

Pentaaqua[2-(5-carboxylato-2-oxido-1-pyridinio)acetato]zinc(II) monohydrate