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The title compound, [Co(C 30 H 23 O 2 P 2 )(C 3 H 9 P) 2 ], was synthesized by the addition of a Co(PMe 3 ) 4  solution to (PPh 2 O) 2 C 6 H 4 . The Co I  atom displays a trigonal-bipyramidal geometry with the two P atoms of the ‘PCP’ pincer ligand and the P atom of one of the trimethyl phosphine ligands forming the basal plane, whereas the metalated C atom and the P atom of the second phospine ligand occupy the apical sites. The Co—C distance is 1.961 (2) Å and the C—Co—P angle is 171.96 (6)°.

[2,6-Bis(diphenylphosphinooxy)phenyl]bis(trimethylphosphine)cobalt(I)