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In the title compound, [CuCl 2 (C 27 H 32 N 2 )], which bears a chiral diamine ligand,  viz  ( R , R )- N , N , N ′′- tribenzyl­cyclo­hexane-1,2-diamine, the Cu II  ion is ligated by two N and two Cl atoms in a distorted square-planar geometry. The coordination of the ligands to the Cu II  ion results in the formation of a five-membered heterocyclic ring and a chiral center at the monosubstituted nitro­gen in an ( S )-configuration. The catalytic capacity of the complex for the asymmetric nitro­aldol reaction is promising (49% ee).

acta crystallographica. section e

Dichlorido[(R,R)-N1,N1,N2-tribenzylcyclohexane-1,2-diamine-κ2N1,N2]copper(II)