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In the crystal structure of the title complex, [Cu(C 6 H 4 N 5 ) 2 (CH 3 OH) 2 ]  n  , the Cu II  cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN 4 O 2  octa­hedral geometry. Each 5-(3-pyrid­yl)tetra­zolate anion bridges two Cu II  cations, forming a two-dimensional polymeric complex with (4,4) network topology. In the crystal structure, the two-dimensional layers are connected by inter­molecular O—H⋯N hydrogen bonding, forming a three-dimensional supra­molecular architecture.

Poly[dimethanolbis[μ-5-(3-pyridyl)tetrazolato-κ2N2:N5]copper(II)]

Poly[dimethanolbis[μ-5-(3-pyridyl)tetrazolato-κ²N²:N⁵]copper(II)]