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The title complex, [Cu(C 7 H 3 NO 4 )(C 7 H 6 N 2 )(H 2 O)]·0.75H 2 O, consists of discrete monomeric units. The Cu II  atom is coordinated by two carboxyl­ate O atoms and the N atom from a dipicolinate unit and by an N atom from a benzimidazole ligand. The distorted square-pyramidal geometry is completed by a longer axial bond to the O atom of a water mol­ecule. The mol­ecular structure and packing are stabilized by classical O—H⋯O and N—H⋯O hydrogen bonds, also including a disordered crystal water molecule.

acta crystallographica. section e

Aqua(1H-benzimidazole-κN3)(pyridine-2,6-dicarboxylato-κ3O2,N,O6)copper(II) 0.75-hydrate