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In the title polymeric compound, {[Cd(C 15 H 11 N 2 O 2 ) 2 ]·0.1H 2 O}  n  , the Cd II  atom is coordinated by four carboxyl­ate O atoms and two benzimidazole N atoms from four benzimidazolylmethyl­benzoate anions in a distorted octa­hedral geometry. Each anion bridges two Cd atoms through the terminal carboxyl­ate group and an imidazole N atom, forming polymeric complex chains running along the  b  axis. The uncoordinated water mol­ecule is equally disordered over two sites; occupancies were fixed as 0.5 for each disordered component. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.

Poly[[{μ2-3-[(1H-benzimidazol-1-yl)methyl]benzoato}cadmium(II)] 0.1-hydrate]

Poly[[{μ₂-3-[(1H-benzimidazol-1-yl)methyl]benzoato}cadmium(II)] 0.1-hydrate]