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The title compound, [Cu 3 (C 5 HN 2 O 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 4 ]·2H 2 O,  is a trinuclear copper(II) complex in which two centrosymmetrically related pyrazole-3,5-dicarboxyl­ate(3−) and 1,10-phenanthroline ligands bind three Cu II  atoms, with one Cu II  atom located on a center of symmetry. In each complex, there are four coordinated water mol­ecules and two solvent water mol­ecules, which participate in extensive hydrogen-bond patterns. These inter­actions, as well as π–π inter­actions between neighbouring 1,10-phenanthroline ligands [shortest atom-to-atom distance = 3.363 (3) Å], extend the crystal structure into a three-dimensional supra­molecular network.

Tetraaquabis(1,10-phenanthroline)bis[μ2-1H-pyrazole-3,5-dicarboxylato(3−)]tricopper(II) dihydrate

Tetraaquabis(1,10-phenanthroline)bis[μ₂-1H-pyrazole-3,5-dicarboxylato(3−)]tricopper(II) dihydrate