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In the title complex, [Cu(C 14 H 11 NO 4 )(C 12 H 8 N 2 )], the tridentate Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and  l -serine. The Cu II  atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter­molecular O—H⋯O and C—H⋯O hydrogen bonds results in a two-dimensional network structure parallel to (001).

acta crystallographica. section e

{N-[(2-Oxido-1-naphthyl)methylidene]serinato-κ3O,N,O′}(1,10-phenanthroline-κ2N,N′)copper(II)