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In the title complex, [Mn(C 9 H 4 N 2 O 4 )(H 2 O) 2 ]  n  , the Mn II  atom is in a distorted octa­hedral coordination completed by one N atom from one 1 H -benzimidazole-5,6-dicarboxyl­ate ligand, two O atoms from two different 1 H -benzimidazole-5,6-dicarboxyl­ate ligands, and three O atoms from three water mol­ecules. Two bridging water mol­ecules and two bridging carboxyl­ate groups from a 1 H -benzimidazole-5,6-dicarboxyl­ate ligand connect two Mn II  ions into a dimeric structure. In the crystal, extensive inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonding forms a three-dimensional network.

acta crystallographica. section e

Poly[μ2-aqua-aqua(μ3-1H-benzimidazole-5,6-dicarboxylato-κ3N3:O5:O5′)manganese(II)]