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The title compound, [W(C 10 H 14 N 2 )(CO) 5 ], contains five carbonyl ligands and a nicotine ligand in an octa­hedral arrangement around the tungsten atom. The metal atom shows  cis  angles in the range 87.30 (16)–94.2 (2)°, and  trans  angles between 175.2 (2) and 178.1 (4)°. The W—CO bond  trans  to the pyridine N atom [1.987 (6) Å] is noticeably shorter than the others, which range between 2.036 (3) and 2.064 (3) Å, possibly due to the well-known  trans  effect. The distance between the W atom and the pyridine N atom is 2.278 (4) Å.

Pentacarbonyl{3-[(2S)-1-methylpyrrolidin-2-yl]pyridine}tungsten(0)