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In the title complex, [Cu(C 9 H 6 N 2 O 5 )(H 2 O) 2 ]·2H 2 O, the Cu II  atom has a square-pyramidal coordination environment with a tridentate  N -(5-nitro-2-oxidobenzyl­idene)glycinate Schiff base ligand and a water mol­ecule in the basal plane. The apical site is occupied by an O atom from another coordinated water mol­ecule. The crystal structure is stabilized by O—H⋯O hydrogen bonds, building a two-dimensional network parallel to (100).

Diaqua[N-(5-nitro-2-oxidobenzylidene)glycinato]copper(II) dihydrate