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The title Cu II  complex, [CuBr 2 (C 21 H 15 N 3 )]·0.5H 2 O, was obtained by the hydro­thermal reaction of copper(II) bromide, 4′-phenyl-2,2′:6′,2′′-terpyridyl (4′-Ph-terpy or  L ) and sodium citrate in water in 31% yield. There are two unique complex mol­ecules and a water mol­ecule in the asymmetric unit. The Cu II  cation is ligated by three N atoms of  L  and two bromide anions, forming an irregular CuN 3 Br 2  polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O—H⋯Br hydrogen bonds link the mol­ecules in a three-dimensional network.

Dibromido(4′-phenyl-2,2′:6′,2′′-terpyridyl)copper(II) hemihydrate