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The title compound, [Mn 2 (C 6 H 8 O 4 S)(C 10 H 8 N 2 ) 4 ](ClO 4 ) 2 , which was crystallized from an aqueous solution, features two Mn II  atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2′-bipyridine ligands and two O atoms of two different 3,3′-sulfanediyldipropionate ( L ) ligands, with the O atoms in  cis  positions. The two carboxyl­ate groups of each  L  ligand, which adopt a  syn-anti  coordination mode, combine with four Mn II  atoms, yielding one-dimensional chains extending along [010].

catena-Poly[[[bis(2,2′-bipyridine)manganese(II)]-μ4-3,3′-sulfanediyldipropionato] bis(perchlorate)]

catena-Poly[[[bis(2,2′-bipyridine)manganese(II)]-μ₄-3,3′-sulfanediyldipropionato] bis(perchlorate)]