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In the title compound, C 16 H 24 NO + ·Br − ·C 20 H 14 O 2 , the  N -hetero­cyclic six-membered ring assumes a half-chair conformation. The two naphthalene ring systems are nearly perpendicular to one another, making a dihedral angle of 89.5 (2)°. Inter­molecular O—H⋯Br hydrogen bonding helps to stabilize the crystal structure.

(3S,NR)-3-Hydroxymethyl-2-methyl-2-(3-methylbut-2-en-1-yl)-1,2,3,4-tetrahydroisoquinolinium bromide–1,1′-bi-2-naphthol (1/1)