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In the title salt, (C 20 H 26 N 2 O 2 )[FeCl 4 ]Cl·H 2 O, the Fe III  atom exists in a tetra­hedral coordination environment. The cation, anions and water mol­ecules are linked by N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds into a layer network.

2-[(R)-Hydroxy(6-methoxyquinolinium-4-yl)methyl]-8-vinyl-1-azoniabicyclo[2.2.2]octane tetrachloridoferrate(III) chloride monohydrate