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With the exception of the terminal hydr­oxy group [N—C—C—O = 53.8 (5)°], the cation of the title salt hydrate, C 5 H 14 NO + ·C 14 H 9 O 4 S 2−. H 2 O, is a straight chain. A twisted conformation is found for the anion [C—S—S—C = −87.44 (16)°]. In the crystal, the anions self-assemble into a helical supra­molecular chain  via  charge-assisted O—H⋯O c  hydrogen bonds. These chains are connected into a three-dimensional network  via  N—H⋯O c , N—H⋯O w , O h —H⋯O cb , and O w —H⋯O c  hydrogen-bonding inter­actions (c = carboxyl­ate, w = water, h = hydr­oxy and cb = carbon­yl).

(2-Hydroxyethyl)(propyl)azanium 2-[(2-carboxyphenyl)disulfanyl]benzoate monohydrate