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In the polymeric title complex, {[Mn(O 2 CC 6 H 4 - p -OH) 2 (C 10 H 8 N 2 )]·C 10 H 8 N 2 ·2H 2 O}  n  , the Mn II  atom is coordinated in a distorted octa­hedral geometry defined by four O atoms from three different carboxyl­ate ligands and two  trans -N atoms from two 4,4′-bipyridine ligands. In the crystal structure, an extensive range of O—H⋯O and O—H⋯N hydrogen bonds link the complex and all non-coordinated mol­ecules into a three-dimensional network.

catena-Poly[[[bis(μ-4-hydroxybenzoato)bis[(4-hydroxybenzoato)manganese(II)]]-di-μ-4,4′-bipyridine] 4,4′-bipyridine disolvate tetrahydrate]