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In the chiral title compound, C 14 H 17 ClO 7 S, an inter­mediate in the synthesis of the AIDS treatment drug zidovudine, the threose ring adopts an envelope configuration, with the O atom at the flap position.

Methyl 5-O-(4-chlorobenzoyl)-2-deoxy-3-O-methylsulfonyl-threo-pentofuranoside