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In the title hydrate, C 18 H 20 BrO 4 P·H 2 O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an  S -configuration. The crystal structure features supra­molecular double chains along the  b  axis mediated by O hydrox­yl –H⋯O oxo , O water –H⋯O oxo , and O water –H⋯O water  hydrogen bonds.

Ethyl [1-(4-bromophenyl)-1-hydroxy-3-oxobutyl](phenyl)phosphinate monohydrate