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The title compound, [CoCl(2)(C(11)H(15)N(3)O(2)Si)(2)]·C(3)H(7)NO, was synthesized from 5-nitro-1-trimethyl-silylmethyl-1H-benzimid-azole and cobalt(II) chloride in dimethyl-formamide. The Co(II) atom is coordinated in a distorted tetra-hedral environment by two Cl atoms and two N atoms. In the crystal structure, there are a number of C-H⋯Cl and C-H⋯O hydrogen-bonding inter-actions between symmetry-related mol-ecules.

Dichloridobis[5-nitro-1-trimethylsilylmethyl-1H-benzimidazole-κN3]cobalt(II)N,N-dimethylformamide solvate

Dichloridobis[5-nitro-1-trimethylsilylmethyl-1H-benzimidazole-κN³]cobalt(II)N,N-dimethylformamide solvate