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The title compound, [Fe(C 16 H 11 N 2 O) 2 ]N 3 , consists of a [Fe(qsal) 2 ] +  cation [Hqsal =  N -(8-quinol­yl)salicylaldimine] and an azide anion. The Fe III  ion, lying on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two tridentate qsal ligands in an octa­hedral geometry. The mol­ecules are connected into a three-dimensional network by inter­molecular C—H⋯N and C—H⋯O inter­actions. π–π inter­actions [inter­planar distance = 3.58 (1) Å] between the quinoline rings of adjacent mol­ecules further stabilize the crystal structure.

Bis[2-(8-quinolyliminomethyl)phenolato-κ3N,N′,O]iron(III) azide

Bis[2-(8-quinolyliminomethyl)phenolato-κ³N,N′,O]iron(III) azide