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The title compound, {[Cu 2 (C 8 H 5 Cl 2 O 3 )(C 10 H 8 N 2 ) 2 ]NO 3 }  n   was prepared by reacting copper(II) nitrate with 4,4′-bipyridine (4,4′-bipy) and (2,4-dichloro­phen­oxy)acetic acid under solvothermal conditions. Each of two copper(I) atoms in the asymmetric unit is three-coordinated by two N atoms from two 4,4′-bipy ligands and one O atom from the (2,4-dichloro­phen­oxy)acetate ligand. As both ligands act as bridging ligands, a double-stranded chain structure is observed.

Poly[[bis(μ2-4,4′-bipyridine)[μ2-(2,4-dichlorophenoxy)acetato]copper(I)] nitrate]

Poly[[bis(μ₂-4,4′-bipyridine)[μ₂-(2,4-dichlorophenoxy)acetato]copper(I)] nitrate]