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The title compound, C 12 H 8 BBr, crystallizes with three essentially planar mol­ecules (r.m.s. deviations = 0.018, 0.020 and 0.021Å) in the asymmetric unit: since the title compound is rigid, there are no conformational differences between these three mol­ecules. The crystal packing resembles a herringbone pattern.

9-Bromo-9-borafluorene