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In the trinucler Cu II  complex mol­ecule of the title compound, [Cu 3 (C 5 HN 2 O 4 ) 2 (H 2 O) 8 ]·4H 2 O, the central Cu II  atom is located on an inversion centre and is coordinated in a distorted octa­hedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-3,5-dicarboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. The two other symmetry-related Cu II  atoms are penta­coordinated and assume a square-pyramidal geometry. In the crystal structure, coordinated and uncoordinated water mol­ecules and carboxyl­ate O atoms are linked by O—H⋯O hydrogen bonds.

Octaaquabis(μ2-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate

Octaaquabis(μ₂-1H-pyrazole-3,5-dicarboxylato)tricopper(II) tetrahydrate