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The title mol­ecule, C 12 H 12 N 2 O 6 , features an  E  conformation about the oxime group. The methoxy­imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and −77.85 (13)°, respectively] to the carbonyl and nitro­phenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C—H⋯O contacts.

Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate