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In the title compound, [Cu(C 5 HF 6 O 2 ) 2 (C 3 H 4 N 2 Se) 2 ], the Cu II  atom (site symmetry) is coordinated by two  O , O ′-bidentate 1,1,1,5,5,5-hexa­fluoro-2,4-penta­nedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole mol­ecules, resulting in a slightly distorted  trans -CuN 2 O 4  octa­hedral geometry in which the  cis  angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the penta­nedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant inter­molecular inter­actions in the crystal.

acta crystallographica. section e

trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ2O,O′)bis(4-methyl-1,2,3-selenadiazole-κN3)copper(II)