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The asymmetric unit of the title compound, C 5 H 7 N 52+ ·2C 7 H 7 O 3 S − ·H 2 O, consists of one diprotonated adeninium cation, two  p -toluene­sulfonic acid anions and one water mol­ecule. In the crystal, the cations and anions are connected through N—H⋯O hydrogen bonds forming  R22 (8) and  R22 (9) graph-set motifs. The solvent water mol­ecule links cations and anions through O—H⋯O and N—H⋯O hydrogen bonds, generating a two-dimensional layer parallel to (10    ).

6-Amino-9H-purine-1,7-diium bis(4-methylbenzenesulfonate) monohydrate