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The title compound, C 7 H 14 BrN 2+ ·Br − , was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diaza­bicyclo­[2.2.2]octa­ne) with dibromo­methane in acetone. The structure features Br⋯H close contacts (2.79 and 2.90 Å) as well as a weak bromine–bromide inter­action [3.6625 (6) Å].

1-Bromomethyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide