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The title compound, C 14 H 21 Cl 3 O 9 ·2H 2 O, is a disaccharide constructed from a galactose and a fructose. In the mol­ecular structure, the tetra­hydro­furan five-membered ring and tetra­hydro­pyran six-membered ring assume envelope and chair conformations, respectively. An extensive O—H⋯O hydrogen-bonding network occurs in the crystal structure.

acta crystallographica. section e

{6-[2,5-Bis(chloromethyl)-3,4-dihydroxytetrahydrofuran-2-yloxy]-3-chloro-4,5-dihydroxy-3,4,5,6-tetrahydro-2<i>H</i>-pyran-2-yl}methyl acetate dihydrate

{6-[2,5-Bis(chloromethyl)-3,4-dihydroxytetrahydrofuran-2-yloxy]-3-chloro-4,5-dihydroxy-3,4,5,6-tetrahydro-2H-pyran-2-yl}methyl acetate dihydrate