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In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl 2 (C 18 H 18 N 4 )]·C 18 H 18 N 4 }  n  , the tetrahedrally coordinated Zn II  ions are linked by the  N -heterocycle into a linear chain. Another  N -heterocycle present is not coordinated to the metal atom but inter­acts with the chain through N—H⋯N and N—H⋯Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511 (4):0.289 (5):0.200 (5) ratio.

acta crystallographica. section e

catena-Poly[[[dichloridozinc(II)]-μ-1,4-bis(1H-benzimidazol-2-yl-κN3)butane] 1,4-bis(1H-benzimidazol-2-yl)butane solvate]