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In the title compound, C 14 H 21 FNO 6 P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the  a -axis direction. A C—H⋯O inter­action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components.

Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate