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The crystal structure of the title compound, [Na(C 3 H 3 N 2 S 3 )(H 2 O) 2 ]  n  , features polymeric chains made up of O⋯O edge-shared NaSN(H 2 O) 4  units running along the  b  axis. The Na +  ion and all non-H atoms of the thia­diazole ligand lie on a mirror plane.

catena-Poly[[(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato)sodium]di-μ-aqua-κ4O:O]

catena-Poly[[(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato)sodium]di-μ-aqua-κ⁴O:O]