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In the centrosymmetric title compound, [Sn 4 Br 2 (C 6 H 5 ) 8 O 2 (OH) 2 ], the four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn 2 O 2  squares. The two independent tin atoms show distorted trigonal-bipyramidal SnC 2 O 3  and SnC 2 O 2 Br coordination geometries.

Dibromidodi-μ-hydroxido-di-μ3-oxido-octaphenyltetratin(IV)

Dibromidodi-μ-hydroxido-di-μ₃-oxido-octaphenyltetratin(IV)