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In the title compound, [Zn(N 3 ) 2 (C 10 H 9 N 3 )]  n  , tetra­hedrally coordinated Zn II  ions with two monodentate azide ligands are linked into zigzag one-dimensional chain motifs by di-4-pyridylamine (dpa) tethers. Individual [Zn(N 3 ) 2 (dpa)]  n   chains are connected into supra­molecular layers  via  N—H⋯N hydrogen bonding between the central amine groups of the dpa ligands and terminal unligated azide N atoms. The azide ligands in one supra­molecular layer penetrate through the neighboring layers above and below, allowing stacking into a three-dimensional structure.

catena-Poly[[diazidozinc(II)]-μ-di-4-pyridylamine-κ2N:N′]

catena-Poly[[diazidozinc(II)]-μ-di-4-pyridylamine-κ²N:N′]