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In the heterometallic dinuclear title compound, [CuNa(C 24 H 22 N 2 O 4 )Cl(H 2 O)]·C 3 H 7 NO, the Cu II  ion is coord­inated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­­idyne)]diphenolate ligand. The Na I  ion is hexa­coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol­ecule and one Cl atom occuping axial positions. The Cu II  and Na I  ions are bridged by two phenolate O atoms.

Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I)N,N-dimethylformamide solvate