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In the title compound, [Ag 2 (C 2 N 3 ) 2 (C 10 H 8 N 2 )]  n  , the Ag atoms, lying on inversion centers, are separated by 3.3226 (12) Å. Each Ag atom is connected by one bridging 4,4′-bipyridine [Ag—N = 2.177 (4)Å] and a terminal dicyanamide [Ag—N = 2.108 (4) Å]. The Ag—Ag interactions play a key role in constructing a unique neutral polymeric chain.

catena-Poly[[bis[(dicyanamido)silver(I)](Ag—Ag)]-μ2-4,4′-bipyridine-κ2N:N′]

catena-Poly[[bis[(dicyanamido)silver(I)](Ag—Ag)]-μ₂-4,4′-bipyridine-κ²N:N′]