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The title compound, C 17 H 16 ClN 5 ·C 3 H 7 NO, was prepared by reaction of  p -toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra­molecular C—H⋯N inter­action occurs. The packing is stabilized by N—H⋯N and N—H⋯O hydrogen bonds and C—H⋯π and π–π [centroid–centroid distance = 3.763 (1) Å] inter­actions.

6-Chloro-N2,N4-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethylformamide monosolvate

6-Chloro-N²,N⁴-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethylformamide monosolvate